Well first of all, 'kg' means mass, not weight.
If the total mass of all his baggage is 35 kg, and the mass 
of his backpack is 4 kg, then the combined mass of all of his 
checked bags is  (35 - 4)  =  31 kg.
If all of his checked bags have the same mass, then the mass
of each one is
                        (31 kg / 222 bags)  =  139.64  grams/bag   (rounded)